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?:abstract
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The continuous growth of the pharmaceutical drug industry has escalated the problem of pharmaceutical waste disposal, and subsequent contamination of aquatic bodies. Paracetamol is one of the most prescribed and purchased drugs that has been widely detected in wastewater and surface water. The present study investigated paracetamol degradation by photocatalytic treatment in a batch system using TiO2 supported on aluminosilicate recovered from waste LED panel (ATiO2). The prepared ATiO2 catalyst was characterized for morphology, elemental composition and crystallinity using scanning electron microscope (SEM) with electron dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), respectively. ATiO2 was spherical in morphology with a predominance of the anatase phase of TiO2 and an average size of â¼15 nm. Subsequently, the effects of operating parameters, viz., initial paracetamol concentration (1-10 mg/L), catalyst dosage (0.5-4.0 g/L) and pH (4-10) on paracetamol degradation were investigated using central composite design (CCD). A polynomial model was developed to interpret the linear and interactive effect of operating parameters on the paracetamol degradation efficiency. About 99% degradation efficiency of paracetamol was obtained at optimum conditions (Initial paracetamol concentration â¼2.74 mg/L, ATiO2 dosage â¼2.71 g/L and pH â¼ 9.5). The mechanism of paracetamol degradation was adsorption on aluminosilicate and subsequent degradation by TiO2. ATiO2 could be effectively reused up to 3 cycles, with <5% decrease in the degradation efficiency.
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