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Catalysis of the reaction: pyruvate + lipoamide = S-acetyldihydrolipoamide + CO2. [EC:1.2.4.1]
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Catalysis of the reactions: pyranose + acceptor = 2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor, and a pyranoside + acceptor = a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor. [EC:1.1.99.29]
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