PropertyValue
?:abstract
  • We report the synthesis, characterization, and electronic state of a novel mixed-valent metal-organic ladder (MOL) linked by pyrazine (pz). Single-crystal X-ray studies revealed that the MOL has a two-legged ladder-shaped framework, which is composed of a pz-connected Pt dimer with bridging Br ions. The electronic state of the MOL was investigated using X-ray and spectroscopic techniques; the MOL was found to have an electronic state that corresponds to the mixed-valence state of PtII and PtIV. Furthermore, the intervalence charge transfer energy of the MOL has lower than that expected from the tendency of a similar halogen-bridged mixed-valence MOL owing to its unique \'zig-zag\'-shaped legs. These results provide a new insight into the physical and electronic properties of MOL systems.
?:creator
?:doi
  • 10.1088/1361-648x/abbbc7
?:doi
?:journal
  • Journal_of_physics._Condensed_matter_:_an_Institute_of_Physics_journal
?:license
  • unk
?:pmid
?:pmid
  • 32977321.0
?:publication_isRelatedTo_Disease
?:source
  • Medline
?:title
  • A Mixed-Valent Metal-Organic Ladder Linked by Pyrazine.
?:type
?:year
  • 2020-09-25

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