PropertyValue
?:abstract
  • Herein we report an iron-catalyzed, convenient and expedient strategy for the synthesis of styrene and naphthalene deriva-tives with the liberation of dihydrogen. The use of a catalyst derived from an earth-abundant metal provides a sustainable strategy to olefins. This method exhibits wide substrate scope (primary and secondary alcohols) functional group tolerance (amino, nitro, halo, alkoxy, thiomethoxy, and S- and N-heterocyclic compounds) and can be scaled up. The unprecedented synthesis of 1-methyl naphthalenes proceeds via tandem methenylation / double dehydrogenation. Mechanistic study shows that the cleavage of the C-H bond of alcohol is the rate determining step.
is ?:annotates of
?:creator
?:doi
  • 10.1021/acs.joc.0c01173
?:doi
?:journal
  • The_Journal_of_organic_chemistry
?:license
  • unk
?:pmid
?:pmid
  • 32600041.0
?:publication_isRelatedTo_Disease
?:source
  • Medline
?:title
  • Iron-Catalyzed Direct Julia-type Olefination of Alcohols.
?:type
?:year
  • 2020-06-29

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