PropertyValue
?:abstract
  • Prussian blue (PB) and its analogues (PBAs) have at least a three-century long history in coordination chemistry. Recently, cobalt-based PBAs have been acknowledged as efficient and robust water oxidation catalysts. Given the flexibility in their synthesis, the structure and morphology of cobalt-based PBAs have been modified for enhanced catalytic activity under electrochemical (EC), photocatalytic (PC), and photoelectrochemical (PEC) conditions. Here, in this review, the work on cobalt-based PBAs is presented in four sections: i) electrocatalytic water oxidation with bare PBAs, ii) photocatalytic process in the presence of a photosensitizer (PS), iii) photoelectrochemical water oxidation by coupling PBAs to proper semiconductors (SCs), and iv) the utilization of PBA-PS assemblies coated on SCs for the dye-sensitized photoelectrochemical water oxidation. This review will guide readers on the structure & catalytic activity relationship in cobalt-based PBAs by describing the role of each structural component. Furthermore, this review aims to provide insight into common strategies to enhance the catalytic activity of PBAs.
is ?:annotates of
?:creator
?:doi
  • 10.1002/chem.202004091
?:doi
?:journal
  • Chemistry
?:license
  • unk
?:pmid
?:pmid
  • 33197292
?:publication_isRelatedTo_Disease
is ?:relation_isRelatedTo_publication of
?:source
  • Medline
?:title
  • How to Build Prussian Blue-Based Water Oxidation Catalytic Assemblies? Common Trends and Strategies.
?:type
?:year
  • 2020-11-16

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